Aquabis(3′-hydroxy-2,2′-bipyridine-3-olato-κ2 N,N′)zinc(II)
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منابع مشابه
Aquabis(3′-hydroxy-2,2′-bipyridine-3-olato-κ2 N,N′)zinc(II)
In the title complex, [Zn(C(10)H(7)N(2)O(2))(2)(H(2)O)], the Zn(II) ion and water O atom are located on a crystallographic twofold rotation axis and the metal atom assumes a distorted trigonal-bipyramidal ZnN(4)O coordination geometry. An intra-molecular O-H⋯O hydrogen bond occurs within the ligand and inter-molecular O-H⋯O hydrogen bonds involving the water mol-ecule result in a sheet structur...
متن کامل(μ-4,4′-Bipyridine-κ2 N:N′)bis[triaqua(4,4′-bipyridine-κN)(3-nitrophthalato-κO 2)cobalt(II)]
The title binuclear complex, [Co(2)(C(8)H(3)NO(6))(2)(C(10)H(8)N(2))(3)(H(2)O)(6)], has been synthesized hydro-thermally from 3-nitro-phthalic acid (H(2)NPA), Co(NO(3))(2)·6H(2)O and 4,4'-bipyridine (4,4'-bipy). The mol-ecule of the complex occupies a special position on an inversion centre. The Co(II) atom has a slightly distorted octa-hedral environment formed by two N atoms from two 4,4'-bip...
متن کاملcatena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ2 O 2:O 3] [[(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ2 O 2:O 3]]
In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordin-ated by two O atoms from two different 3-chloro-benzene-1,2-dicarboxyl-ate ligands, one O atom from a water mol-ecule and two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, while the second Zn(2+) ion is four-coordinated by two O atoms from two diffe...
متن کاملDiaquabis(9-oxo-4,5-diazafluoren-3-olato-κ2 N 4,O 3)cadmium(II)
The title compound, [Cd(C(11)H(5)N(2)O(2))(2)(H(2)O)(2)], is a mononuclear complex consisting of a Cd(II) atom, two 3-hydr-oxy-4,5-diaza-fluoren-9-one ligands and two coordinated water mol-ecules. The Cd(II) atom, lying on a twofold axis, displays a distorted octa-hedral coordintion. Adjacent mol-ecules are linked by O-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.84 ...
متن کاملcatena-Poly[[bis(3-methylbenzoato-κ2 O,O′)lead(II)]-μ-4,4′-bipyridine-κ2 N:N′]
In the title complex, [Pb(C(8)H(7)O(2))(2)(C(10)H(8)N(2))](n), the Pb(II) atom is located on a twofold rotation axis and is six-coordinated by four carboxyl-ate O atoms from two 3-methyl-benzoate ligands and two N atoms from two 4,4'-bipyridine (4,4'-bpy) ligands, displaying a hemi-directed coordination. The 4,4'-bpy ligand has an inversion center at the mid-point of the central C-C bond. The P...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808024495